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銆�?銆佺籍顙絘(ch菐n)閬庣▼涓�鐒℃瘨鐒℃薄鏌�;
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銆�銆�1839骞达紝Becquerel鐧�(f膩)鐝�(xi脿n)姘у寲閵呮垨楣靛寲閵�娑傚湪閲戝爆闆绘サ涓婃渻(hu矛)鐢�(ch菐n)鐢熷厜闆荤従(xi脿n)璞�锛岃瓑瀵�(sh铆)浜嗗厜闆昏綁(zhu菐n)鎻涚殑鍙�鑳姐��1960骞翠唬锛孒.Gerischer锛孒.Tributsch锛孧eier鍙奟.Memming鐧�(f膩)鐝�(xi脿n)鏌撴枡鍚搁檮鍦ㄥ崐灏�(d菐o)楂斾笂骞跺湪涓�瀹氭�濅欢涓嬬��(ch菐n)鐢熼浕娴佺殑鐝�(xi脿n)璞�锛屾垚鐐哄厜闆诲寲瀛�(xu茅)闆绘睜鐨勯噸瑕佸熀绀�(ch菙)銆�
銆�銆�1980骞翠唬,鍏夐浕杞�(zhu菐n)鎻涚爺绌剁殑閲嶉粸(di菐n)杞�(zhu菐n)鍚戜汉宸ユā鎿�鍏夊悎浣滅��锛岀編鍦嬪窞绔婣rizona澶у��(xu茅)鐨凣ust鍜孧oore鐮旂┒灏忕祫鎴愬姛妯℃摤浜嗗厜鍚堜綔鐢ㄤ腑鍏夐浕瀛愯綁(zhu菐n)鎻涢亷绋嬶紝骞跺彇寰椾簡涓�瀹氱殑鎴愮妇銆侳ujihia绛夊皣鏈夋��(j墨)澶氬厓鍒嗗瓙鐢↙B鑶滅祫瑁濇垚鍏夐浕浜屾サ绠★紝闁嬫嫇浜嗛�欐柟闈㈢殑宸ヤ綔銆�
銆�銆�1970骞翠唬鍒�90骞翠唬锛孯.Memming锛孒.Gerischer锛孒auffe锛孒.Tributsh绛変汉澶ч噺鐮旂┒浜嗗悇绋�鏌撴枡鏁忓寲鍔戣垏鍗婂��(d菐o)楂旂磵绫虫櫠闁撳厜鏁忓寲浣滅敤锛岀爺绌朵富瑕侀泦涓�鍦ㄥ钩鏉块浕妤典��锛岄�欓�為浕妤靛彧鏈夎〃闈㈠惛闄勫柈灞ゆ煋鏂�锛屽厜闆昏綁(zhu菐n)鎻涙晥鐜囧皬浜�1%銆�
銆�銆�1991骞�锛孏rätzelM.浜庛�奛ature銆嬩笂鐧�(f膩)琛ㄤ簡闂�(gu膩n)浜庢煋鏂欐晱鍖栫磵绫虫櫠楂斿お闄借兘闆绘睜鐨勬枃绔犱互杓冧綆鐨勬垚鏈�寰楀埌浜�>7%鐨勫厜闆昏綁(zhu菐n)鍖栨晥鐜囷紝闁嬭緹浜嗗お闄借兘闆绘睜鐧�(f膩)灞曞彶涓婁竴鍊�(g猫)宥勬柊鐨勬檪(sh铆)浠�,鐐哄埄鐢ㄥお闄借兘鎻愪緵浜嗕竴姊濇柊鐨勯�斿緫銆�
銆�銆�1993骞�,GrätzelM.绛変汉鍐嶆�＄爺鍒跺嚭鍏夐浕杞�(zhu菐n)鎻涙晥鐜囬仈(d谩)10%鐨勬煋鏂欐晱鍖栧お闄借兘闆绘睜,宸叉帴杩戝偝绲�(t菕ng)鐨勭�呭厜浼忛浕姹犵殑姘村��銆�
銆�銆�1997骞�锛岃┎闆绘睜鐨勫厜闆昏綁(zhu菐n)鎻涙晥鐜囬仈(d谩)鍒颁簡10%-11%锛岀煭璺�闆绘祦閬�(d谩)鍒�18mA/cm2,闁嬭矾闆诲�撻��(d谩)鍒�720mV銆�
銆�銆�1998骞�锛岄噰鐢ㄥ浐楂旀湁姗�(j墨)绌虹┐鍌宠几鏉愭枡鏇夸唬娑查珨闆昏В璩�(zh矛)鐨勫叏鍥烘厠(t脿i)Grätzel闆绘睜鐮斿埗鎴愬姛锛屽叾鍠�鑹插厜闆昏��(zhu菐n)鎻涙晥鐜囬仈(d谩)鍒�33%锛屽緸鑰屽紩璧蜂簡鍏ㄤ笘鐣岀殑闂�(gu膩n)娉�銆�
銆�銆�2000骞�锛屾澅鑺濆叕鍙哥爺绌朵汉鍝￠枊鐧�(f膩)鍚�纰�/纰樺寲鐗╃殑鏈夋��(j墨)铻嶉菇鍑濊啝闆昏В璩�(zh矛)鐨勬簴(zh菙n)鍥烘厠(t脿i)鏌撴枡鏁忓寲绱嶇背鏅跺お闄借兘闆绘睜锛屽叾鍏夐浕鑳介噺杞�(zhu菐n)鎻涚巼7.3%銆�
銆�銆�2001骞�,婢冲ぇ鍒╀簽STA鍏�鍙稿缓绔嬩簡涓栫晫涓婂��(g猫)涓�瑭﹁��(gu墨)妯＄殑DSC宸ュ粻銆�
銆�銆�2002骞�,STA寤虹珛浜嗚縿浠婄偤姝㈢殑闈㈢�嶇��200m2DSC椤�绀哄眿闋�,闆嗕腑楂旂従(xi脿n)浜嗘湭渚嗗伐妤�(y猫)鍖栫殑鍓嶆櫙銆�
銆�銆�2002骞碢(gu膩n)engWang绛変汉鐢ㄥ惈鏈�1-methyl-3-propylimidazoliumiodide鍜宲oly(viylidenefloride-cohexafluoropropylene)闆㈠瓙娑叉厠(t脿i)鑱氬悎鐗╁嚌鑶犻浕瑙ｈ唱(zh矛)鐨勬簴(zh菙n)鍥烘厠(t脿i)鏌撴枡鏁忓寲绱嶇背鏅跺お闄借兘闆绘睜锛屽叾鍏夐浕杞�(zhu菐n)鎻涙晥鐜囧彲閬�(d谩)5.3%銆�
銆�銆�2003骞�锛屾棩鏈琄ohjiroHara绛変汉鍫�(b脿o)閬撲簡涓�绋�澶氱儻鏌撴枡鏁忓寲绱嶇背澶�闄借兘闆绘睜锛屽叾鍏夐浕鑳介噺杞�(zhu菐n)鎻涚巼閬�(d谩)6.8%銆�
銆�銆�2003骞�锛屾棩鏈琓amotsuHuriuchi绛変汉闁嬬櫦(f膩)涓�绋�寤夊��(ji脿)鐨刬ndoline鏌撴枡锛屽叾鍏夐浕杞�(zhu菐n)鎻涙晥鐜囧彲閬�(d谩)6.1%銆�
銆�銆�2003骞�锛孉krakawa宸ヤ綔绲勭敤棣欒眴绱犳煋鏂欏仛鏁忓寲鍔戠殑澶�闄借兘闆绘��锛屽叾鍏夐浕杞�(zhu菐n)鎻涙晥鐜囧彲閬�(d谩)7.7%銆�
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